Once you've compiled PHP with cURL support, you can begin using the cURL functions. The basic idea behind the cURL functions is that you initialize a cURL session using the curl_init(), then you can set all your options for the transfer via the curl_setopt(), then you can execute the session with the curl_exec() and then you finish off your session using the curl_close(). Here is an example that uses the cURL functions to fetch the example.com homepage into a file:
Example #1 Using PHP's cURL module to fetch the example.com homepage